Elevated Glyoxal Concentrations over the Eastern Equatorial Pacific: A Direct Biogenic Source?
Elevated Glyoxal Concentrations over the Eastern Equatorial Pacific: A Direct Biogenic Source?
Abstract:
Elevated atmospheric glyoxal (CHOCHO) was observed over the eastern equatorial Pacific by satellite and ship measurements. We investigated the source contributions through inverse modeling using GOME-2 observations (2007-2012) and the GEOS-Chem model. The observed high glyoxal to HCHO column ratio over the region indicates the potential presence of a direct source of glyoxal rather than secondary production. A bimodal seasonal cycle of glyoxal concentrations was found, providing further evidence for a biogenic origin of glyoxal emission. The estimate of the primary glyoxal emission over the eastern equatorial Pacific is 20-40Tg/yr, which is comparable to the previous estimate of the global continential glyoxal emission.
