Soil chemical weathering under morphologic and climatic controls in the Northern Rockies, Montana

Abstract:

Climate influences soil weathering via moisture availability and temperatures, but globally physical erosion rate appears to be a more important control on weathering rate than climate. Understanding these links requires investigation into landscapes where the climate’s influence on weathering is discernable despite the signal of physical erosion rate—in kinetically limited regimes. However, in these systems, rapid erosion rates and complex morphologies add complexity and heterogeneity to soil weathering. 

To investigate the dual controls of landscape morphology and climate on chemical weathering, we quantify soil distribution, thickness, and weathering extent by focusing on catchments within two adjacent mountain ranges in the Northern Rockies. The Bitterroot Mtns present previously-glaciated valleys with steep ridges and high present-day MAP, which contrast with the drier and more gentle, nonglaciated hillslopes of the Sapphire Mtns to the east. We use field and remotely sensed data to quantify soil distribution and thickness, and elemental geochemistry to measure the variability of chemical weathering across these systems.

Mean slopes in the Bitterroots are ~1.3x higher than those in our Sapphire catchment, leading to large differences in soil distribution. Initial mapping of soils using remotely sensed data and rock exposure indices (REI) indicate that ~50% of the Bitterroot system is bare of soil, compared to <5% in the Sapphire system. REIs are distinct between these systems, with ~10˚ difference in slope thresholds for soil cover. Additionally, field data indicate that sparse soils of the Bitterroots are significantly thinner than those in Sapphire system (B=17±2cm, n=161; S=32±3, n=31). Initial XRF data suggest soil weathering intensity is more than two times greater in the Sapphires. These results suggest that the morphologic landscape legacy left by now-extinct glaciers imposes a kinetic limitation on soil weathering, even despite high modern moisture availability.