Study of Geochemical System in Constructed Wetland Using Multivariate Statistical Analysis

Abstract:

People have recognized that the human activities lead to the degradation of the environment, and constructed wetland is one of the well-known technologies for water treatment. In constructed wetland, complicated processes should be considered such as redox reactions, acid-base reactions, adsorption-desorption between water and sediment and biochemical reactions associated with plant and microorganism. In this study, most of inorganic components were analyzed and principal component analysis (PCA) was followed for depicting the controlling biochemical reaction in the constructed wetland. The results could be a guide to operate the constructed wetland.

The constructed wetland in this study is located in Taoyuan County, north Taiwan. It’s a horizontal subsurface flow constructed wetland composed of ten cells. The water in wetland was pumped from Nankan River, which collects wastewater from Hwaya technology park, Linkou, Guishan and Nankan industrial zone. The water of inflow and outflow from each cell were collected for analyzing inorganic components with ICP-MS and IC. In general, the results show that water quality had dramatically changed in the first three cells and became stable in the following seven cells.

In this study, PCA extracted two major factors (PCs), which can respectively explain 52.76%（PC1）and 28.32%（PC2）of variance of water quality data. PC1 separates samples of the first three cells from those of the other following cells. It is believed that there was another pollution source involved in the 4^th cell because PC1 is characterized by high loadings of most of trace heavy metals. On the other hand, the hydrochemistry of water mainly evolve along PC2 axis. PC2 is composed of Fe, Mn, NH4, dissolved oxygen, pH, etc with high loadings. These chemical components are predominately controlled by redox reactions. Moreover, the deep water from the 4^th cell contains high concentrations of many heavy metals, especially Cu and Ga. This confirms the previous derivation based on PCA. The rare earth elements (REEs) were also measured in this study. After normalized to North American shale, the REEs shows an uncommon pattern with Eu and Gd positive anomalies and Tm negative anomaly, which probably result from industrial contamination. However, more studies would be needed to prove it.