Thresholds in Soil Mineral Weathering and Relation to Streamwater Chemistry in Glaciated Catchments of the Northeastern USA

Abstract:

Primary mineral dissolution (i.e. weathering) is a critical process in forested catchments as an important consumer of acidity and CO₂, the principle source of nutrients such as Ca, K, and P, as well as the source of toxic cations such as Al. Two common limitations of weathering studies are inadequate determination of mineralogic composition and insufficient sampling depth to determine location and advancement of weathering reactions. We determined mineral stocks through EPMA mapping of Al, Ca, Fe, P, and Si content of soil samples and development of an image analysis routine that assigned mineral composition based on the content of these five elements. Portions of the classified maps were confirmed by optical petrography and full elemental analysis by SEM-EDS. Samples were analyzed for soil profiles >2m depth (~1.5m past the upper boundary of the “unweathered” C horizon). Study sites spanned a range of weatherability found in catchments in glaciated northeastern USA including Winnisook, NY (sandstone parent material, 100 ppm Ca), Hubbard Brook, NH (granite, 0.9% Ca), and Sleepers River, VT (calcareous granulite, 3.5% Ca). All profiles exhibited a weathering front, or threshold above which the most reactive minerals (calcite, apatite) have been depleted. However, in all cases this threshold was below the rooting zone, and in many profiles, it was well below the C horizon interface. Catchment scale Ca exports reflect this deeper weathering source while rooting zone exchangeable Ca was highly variable, probably reflecting spatial patterns of hydrologic flowpaths which bring deeper weathering products to the surface only in certain landscape positions. These results suggest that nutrient cycling and critical loads models, which assume that ecologically relevant weathering is confined to the rooting zone, need to be refined to account for deeper weathering and spatial patterns of lateral and upward hydrologic fluxes. Similarly, recovery from cultural acidification may be limited in portions of catchments where hydrologic connections do not provide a vehicle for weathering products to recharge the biologically active portion of the subsurface.