B11G-0511
After the Storm: Assessing the carbon and nitrogen leaching potential from sediments deposited in aquatic ecosystems

Monday, 14 December 2015
Poster Hall (Moscone South)
Erin R Johnson1, Chelsea Krieg1, Caraline Canning1, Shreeram P Inamdar2 and Richard Douglas Rowland1, (1)University of Delaware, Water Science and Policy, Newark, DE, United States, (2)University of Delaware, Newark, DE, United States
Abstract:
The erosive energy of large storms can mobilize, and subsequently deposit large amounts of sediment in receiving aquatic ecosystems. Depending on the character of the sediments there is potential for leaching or sequestration of carbon (C) and nitrogen (N) from the sediments. This could have significant implications for water quality, aquatic metabolism, and global cycling of C and N. This study examines the fate of these sediments by: (1) determining the amount and quality of organic matter that can be leached into the surrounding water from coarse, medium and fine particle classes (2) assessing the C and N contents of various particles classes and the sources of the sediment through isotopic composition.

Bed sediment samples were collected along a 1-2nd order stream (eight locations) in a forested catchment in the Piedmont region of Maryland following a large storm event. Samples were sieved into three particle classes – coarse (2mm-1mm), medium (1mm-250µm) and fine (<250µm). Extractions were performed for each of three particle class sizes by leaching with DI water. Organic matter composition for the extracts was characterized using fluorescence. Stable isotopes of 13C and 15N were determined for bed sediment classes and upland source sediments to identify the origins of the eroded sediments.

Extracts with low C:N ratios that also exhibit a higher percent protein and lower percent humic carbon content are considered most labile. Within the bed sediment deposits, differences were found in the distribution of labile compounds between each particle class size. Generally, course particle size exhibited the most labile characteristics, closely followed by medium particle size. Fine particle size exhibited the most refractory characteristics in all locations.

These results are critical since climate-change predictions reveal more intense and large storms for the northeast US, with potentially greater impacts on aquatic ecosystems from eroded upland sediments.