Characteristics of total column ozone and nitrogen dioxide amount over Korea during the 2015 MAPS campaign: Pandora spectrometer, satellite and in-situ measurement

Monday, 14 December 2015
Poster Hall (Moscone South)
Hee Sung Chong1, Woogyung Kim1, Jhoon Kim1, Hana Lee1, Jung Hyun Kim1, Jiyoung KIM1, Jay R Herman2, Nader Abuhassan3 and Jeong-Hoo Park4, (1)Yonsei University, Seoul, South Korea, (2)University of Maryland Baltimore County, Baltimore, MD, United States, (3)NASA Goddard Space Flight Center, Greenbelt, MD, United States, (4)NIER National Institute of Environmental Research, Incheon, South Korea
To improve the performances of satellite retrieval of surface pollution and air quality models, NIER (National Institute of Environmental Research) and NASA are planning the KORUS-AQ campaign over the Korean Peninsula in May-June, 2016. As a pre-campaign of the KORUS-AQ, MAPS (Megacity Air Pollution Studies)-Seoul was conducted from May to July, 2015. During this campaign, six Pandora instruments continuously provided total column density of O3 and NO2 over Korea. These measurements will be continued until the end of 2016 covering the KORUS-AQ campaign period and beyond for the initial validation of TROPOMI measurements. To assess the variation of O3 and NO2, data were collected from Pandora, Dobson spectrophotometer, Brewer spectrophotometer, other ground-based in situ measurements and Ozone Monitoring Instrument (OMI). Ozone column density from Pandora exhibited significantly high correlation (R2 > 0.8) with the ground-based Dobson and Brewer spectrophotometers. Due to the detector anomaly and wide spatial pixel coverage, O3 values from OMI showed lower correlation (R2 > 0.6) with the Pandora. Even though six Pandoras were scattered across the country, O3 data showed similar distribution, in accordance with the low spatial variability of ozone. On the contrary, NO2 distribution pattern showed large difference at each site, which showed peak at around 10 a.m., with larger diurnal variability in urban area than that in rural area by more than 5 times. As most of Pandora sites do not have on-site in situ NO2 measurements, other in situ data from the nearest Air Korea stations were used for the comparison. The comparison result showed significant correlation, although, the correlation coefficient was relatively lower than that of O3. Pandora measurements agreed well with the ground based instruments and OMI satellite data with averaged residuals less than 2% in O3. In case of NO2 Pandora measurements showed similar trend with in situ measurements.