A33E:
Laboratory Studies in Atmospheric Sciences III Posters

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Session ID#: 12873

Session Description:
Laboratory studies are fundamental to developing the knowledge needed to understand atmospheric chemistry over a broad range of conditions and environments and applying that knowledge to observations and models of Earth’s atmosphere. This session focuses on presentations of laboratory studies in areas including, but not limited to:  gas-phase kinetics and product studies (e.g. reactions involving OH, Cl, O3, NO3, Criegee intermediates), heterogeneous chemistry (e.g. reactive uptake, interfacial processes), aqueous phase chemistry (e.g. hydrolysis, photochemistry), chamber studies (e.g. VOC oxidation), spectroscopy (e.g. cross sections, quantum yields), aerosol properties (e.g. SOA formation and aging, nucleation), and reaction mechanism development (e.g. isoprene, monoterpenes, VOCs). The primary focus of this session is on studies in which the laboratory effort plays a central role in producing scientific results. Modeling and theoretical studies that incorporate laboratory data or that present results for conditions where no laboratory data exist (thereby motivating future laboratory experiments) are also encouraged.
Primary Convener:  David M Wilmouth, Harvard University, Cambridge, United States
Conveners:  James B Burkholder, NOAA ESRL, Chemical Sciences Laboratory, Boulder, CO, United States, John D Crounse, California Institute of Technology, Pasadena, CA, United States and Neil McPherson Donahue, Carnegie Mellon University, Center for Atmospheric Particle Studies, Pittsburgh, PA, United States
Chairs:  John D Crounse, California Institute of Technology, Pasadena, CA, United States, James B Burkholder, NOAA ESRL, Chemical Sciences Laboratory, Boulder, CO, United States, Neil McPherson Donahue, Carnegie Mellon University, Center for Atmospheric Particle Studies, Pittsburgh, PA, United States and David M Wilmouth, Harvard University, Cambridge, United States
OSPA Liaison:  David M Wilmouth, Harvard University, Cambridge, United States
Index Terms:

0317 Chemical kinetic and photochemical properties [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0340 Middle atmosphere: composition and chemistry [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0365 Troposphere: composition and chemistry [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0394 Instruments and techniques [ATMOSPHERIC COMPOSITION AND STRUCTURE]

Abstracts Submitted to this Session:

Laboratory Study of the OH + Permethylsiloxane (L2, L3, D3, and D4) Reaction Rate Coefficients Between 240 and 370 K (138557)
James B Burkholder, NOAA ESRL, Chemical Sciences Laboratory, Boulder, CO, United States, François Bernard, NOAA Boulder, ESRL/CSD, Boulder, CO, United States and Vassileios C Papadimitriou, University of Crete, Chemistry, Heraklion, Greece
Laboratory Studies of O-Atom Recombination Relevant to the Earth’s Upper Atmosphere (139113)
Yingdi Liu1, Kelly Neubauer1,2, Daniel Matsiev3 and Konstantinos S. Kalogerakis3, (1)SRI International, Center for Geospace Studies, Menlo Park, CA, United States, (2)Gustavus Adolphus College, Saint Peter, MN, United States, (3)SRI International, Center for Geospace Studies, Menlo Park, United States
Influence of Water on the H2SO4 Yield from the Ozonolysis of 2,3-dimethyl-butene (TME) in Presence of SO2 (156753)
Alexandre Kukui1, Hui Chen1, Daële Véronique2 and Abdelwahid Mellouki3, (1)Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (LPC2E), CNRS, Orléans, France, (2)Centre National de la Recherche Scientifique (ICARE-CNRS)/OSUC, Institut de Combustion Aerothermique, Reactivite et Environnement, Orleans, France, (3)ICARE-CNRS, Orleans, France
Radiative Efficiencies and Atmospheric Loss Processes of Atmospherically Persistent Perfluoroamines: N(CxF2x+1)3, x = 2-5 (160409)
François Bernard1,2, Vassileios C Papadimitriou3, Dimitrios K Papanastasiou2,4 and James B Burkholder5, (1)Cooperative Institute for Research in Environmental Sciences, Boulder, CO, United States, (2)NOAA Boulder, ESRL/CSD, Boulder, CO, United States, (3)University of Crete, Chemistry, Heraklion, Greece, (4)Independent Researcher, Buffalo, NY, United States, (5)NOAA ESRL, Chemical Sciences Laboratory, Boulder, CO, United States
Reaction rates of Criegee intermediates with water vapor and hydrogen sulfide (171168)
Mica C Smith, University of California Berkeley, Chemistry, Berkeley, CA, United States and Kristie A Boering, University of California Berkeley, Chemistry and Earth & Planetary Science, Berkeley, CA, United States
High Accuracy OH Reaction Rate Constant Measurements: Studies of Pressure Dependencies and of the Reactivities of Stereoisomers. (180763)
Vladimir L Orkin1, Victor G Khamaganov1 and Michael J Kurylo III2, (1)National Institute of Standards and Technology Gaithersburg, Gaithersburg, MD, United States, (2)Universities Space Research Association Columbia, Columbia, MD, United States
Temperature- and Pressure-Dependent Kinetics Studies of Atomic Chlorine Reactions with Some Fluorinated Olefins and Ethers (188749)
John Michael Nicovich1, Paul H. Wine1, Shrila Mazumder2, Gregory P. Hatzis3 and Meng Jiang1, (1)Georgia Institute of Technology, Chemistry and Biochemistry, Atlanta, GA, United States, (2)Oak Ridge Institute for Science and Education, Oak Ridge, TN, United States, (3)Brandeis Unversity, Waltham, MA, United States
Rate coefficient for the OH radical reaction with HONO2 under UT/LS conditions (165347)
Frank Winiberg1, Yingdi Liu2 and Stanley P Sander1, (1)NASA Jet Propulsion Laboratory, California Institute of Technology, Pasadena, United States, (2)California Institute of Technology, Pasadena, CA, United States
Characterizing Interferences in an NOy Thermal Dissociation Inlet (177739)
Caroline Womack, NOAA ESRL Chemical Sciences Division, Boulder, CO, United States, Patrick R Veres, NOAA Boulder, Boulder, United States, Charles A Brock, NOAA, Chemical Sciences Laboratory, Boulder, United States, J A Neuman, CIRES, Boulder, CO, United States, Scott Joseph Eilerman, Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, United States, Kyle J Zarzana, NOAA Boulder, Chemical Sciences Division, Earth System Research Laboratory, Boulder, CO, United States, William P Dube, NOAA Boulder, Boulder, CO, United States, Robert J Wild, Colorado University/NOAA/ESRL, Boulder, CO, United States, Paul J Wooldridge, University of California Berkeley, Berkeley, CA, United States, Ronald C Cohen, University of California, Berkeley, Earth and Planetary Science, Berkeley, United States and Steven S Brown, NOAA, Earth System Research Laboratory, Boulder, CO, United States
Pressure- and Temperature-Dependent Branching Ratios of the OH + NO2 Reaction (187706)
Joseph P. Messinger1, Laura A. Mertens1, Damien Amedro1, Mitchio Okumura2 and Stanley Sander3, (1)California Institute of Technology, Chemistry, Pasadena, CA, United States, (2)California Institute of Technology, Division of Chemistry and Chemical Engineering, Pasadena, CA, United States, (3)Jet Propulsion Laboratory, California Institute of Technology, Pasadena, United States
Laboratory Studies of Halogen Oxides Important to Stratospheric Ozone Depletion (187950)
David M Wilmouth1, J. Eric Klobas2 and James G Anderson1, (1)Harvard University, Cambridge, United States, (2)Harvard University, Harvard John A Paulson School of Engineering and Applied Sciences, Cambridge, United States
A model analysis of halogen kinetics: the ClOOCl catalytic cycle revisited (184127)
Timothy P Canty, University of Maryland, College Park, Department of Atmospheric and Oceanic Science, College Park, United States, Ross J Salawitch, University of Maryland College Park, Department of Chemistry and Biochemistry, College Park, United States and David M Wilmouth, Harvard University, Cambridge, United States
Depositional and Immersion-Mode Ice Nucleation of Fine-Grained Volcanic Ash Samples (190409)
Shelby Cloer1, Taylor W. Woods2 and Kimberly D Genareau2, (1)University of Alabama, Tuscaloosa, AL, United States, (2)University of Alabama, Department of Geological Sciences, Tuscaloosa, AL, United States
Nanoparticle Growth and Reactivity (195031)
Murray V Johnston, University of Delaware, Chemistry, Newark, DE, United States
Secondary organic aerosol mass yields from the dark NO3 oxidation of α-pinene and Δ-carene: effect of RO2 radical fate (135842)
Hyungu Kang1,2, Doug A Day3,4, Jordan Krechmer4,5, Benjamin R Ayres1, Natalie I Keehan1, Samantha Thompson2,4, Weiwei Hu2,4, Pedro Campuzano-Jost6, Jason Clay Schroder2,7, Harald Stark5,7, April Ranney8, Paul J Ziemann4,9, Kyle J Zarzana10,11, Robert J Wild2,10, William Dubé2,10, Steven S Brown12,13, Juliane Fry1 and Jose L Jimenez3,7, (1)Reed College, Dept. of Chemistry, Portland, OR, United States, (2)Cooperative Institute for Research in Environmental Sciences, Boulder, CO, United States, (3)Cooperative Institute for Research in Environmental Sciences (CIRES), Boulder, United States, (4)University of Colorado at Boulder, Department of Chemistry & Biochemistry, Boulder, CO, United States, (5)Aerodyne Research Inc., Billerica, United States, (6)University of Colorado Boulder, Department of Chemistry and Cooperative Institute for Research in Environmental Sciences, Boulder, United States, (7)University of Colorado at Boulder, Department of Chemistry, Boulder, CO, United States, (8)University of California Riverside, Environmental Toxicology Graduate Program, Riverside, CA, United States, (9)CIRES, Boulder, CO, United States, (10)NOAA Boulder, Chemical Sciences Division, Earth System Research Laboratory, Boulder, CO, United States, (11)Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, United States, (12)NOAA, Earth System Research Laboratory, Boulder, CO, United States, (13)University of Colorado Boulder, Department of Chemistry and Biochemistry, Boulder, CO, United States
Evaluation of Machine Learning Algorithms for Classification of Primary Biological Aerosol using a new UV-LIF spectrometer (148600)
Simon Timothy Ruske1, David O Topping2, Virginia E Foot3, Paul H Kaye4, Warren R Stanley4, Andrew P Morse5, Ian Crawford6 and Martin William Gallagher6, (1)University of Manchester, Manchester, M13, United Kingdom, (2)University of Manchester, School of Earth, Atmospheric and Environmental Science, Manchester, United Kingdom, (3)Defence Science and Technology Laboratory, Salisbury, United Kingdom, (4)University of Hertfordshire, Hatfield, United Kingdom, (5)University of Liverpool, Liverpool, United Kingdom, (6)University of Manchester, Manchester, United Kingdom
Water Uptake and Optical Properties of Biomass Smoke from Southwestern US Fuels: Predicting Properties and Their Variability (165320)
Christian Carrico1, Samantha L Bixler1, Caroline Allen1, Manvendra Krishna Dubey2, Allison C Aiken3, Thom A Rahn4, Luis Torres5 and Harrison Alexander Parker4, (1)New Mexico Institute of Mining and Technology, Socorro, NM, United States, (2)Los Alamos National Laboratory, Earth and Environmental Sciences, Los Alamos, NM, United States, (3)Los Alamos National Laboratory, Earth and Environmental Science Division, Los Alamos, NM, United States, (4)Los Alamos National Laboratory, Los Alamos, NM, United States, (5)New Mexico Institute of Mining and Technology, Dept of Physics, Socorro, NM, United States
Optical Properties and Aging of Light Absorbing Secondary Organic Aerosol (180642)
Jiumeng Liu1, Peng Lin1, Alexander Laskin1, Julia Laskin1, Shawn M Kathmann1, Matthew Wise2, Ryan Caylor2, Felisha Imholt2, Vanessa Selimovic2 and John Shilling3, (1)Pacific Northwest National Laboratory, Richland, WA, United States, (2)Concordia University, Math and Science Department, Portland, OR, United States, (3)Pacific Northwest National Laboratory, Richland, United States
SOA Formation from a/b-farnesene mixture (182096)
Tadeusz E Kleindienst1, Mohammed Jaoui1, Michael Lewandowski1, John H Offenberg2 and Kenneth Docherty3, (1)U.S. Environmental Protection Agency, National Exposure Research Laboratory, Research Triangle Park, NC, United States, (2)Environmental Protection Agency Research Triangle Park, Research Triangle Park, NC, United States, (3)Jacobs Technology, Inc., RTP, NC, United States
A new look at the Effect of NOx on Biogenic SOA Yields (183524)
John Shilling1, Jiumeng Liu2, Rahul A Zaveri3, Alla Zelenyuk2, David Bell4, Alex B Guenther5, Joel A Thornton6, Emma D'Ambro7, Siegfried Schobesberger8, Cassandra Gaston9, Ben H. Lee10, Mikael Ehn11, Otso Perakyla11, Chao Yan12, Christopher D Cappa13, Taylor Helgestad13, Ziyue Li14, Matthew Wise15, Jian Wang16, Ryan Thalman17, Jason D Surratt18, Zhenfa Zhang18, Theran Riedel19 and Avram Gold20, (1)Pacific Northwest National Laboratory, Richland, United States, (2)Pacific Northwest National Laboratory, Richland, WA, United States, (3)Pacific Northwest Natl Lab, Richland, United States, (4)Universities Space Research Association Moffett Field, Moffett Field, CA, United States, (5)University of California Irvine, Department of Earth System Science, Irvine, CA, United States, (6)University of Washington, Department of Atmospheric and Climate Science, Seattle, United States, (7)Univ Washington - Seattle, Seattle, WA, United States, (8)University of Washington Seattle Campus, Department of Atmospheric Sciences, Seattle, WA, United States, (9)University of Washington Seattle Campus, Seattle, WA, United States, (10)University of Washington Seattle Campus, Department of Atmospheric Sciences, Seattle, United States, (11)University of Helsinki, Helsinki, Finland, (12)Central South University, Changsha, China, (13)University of California Davis, Civil and Environmental Engineering, Davis, CA, United States, (14)University of California Davis, Atmospheric Science, Davis, CA, United States, (15)Concordia University, Math and Science Department, Portland, OR, United States, (16)Brookhaven Natl Lab, Upton, United States, (17)Brookhaven National Laboratory, Upton, NY, United States, (18)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, United States, (19)U.S. Environmental Protection Agency, National Exposure Research Laboratory, Research Triangle Park, NC, United States, (20)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, NC, United States
A New Method Using Single-Particle Mass Spectrometry Data to Distinguish Mineral Dust and Biological Aerosols (199953)
Hashim Al-Mashat1, Louise Kristensen2, Camille Marissa Sultana2 and Kimberly A Prather3, (1)University of California San Diego, Chemistry and Biochemistry, La Jolla, CA, United States, (2)University of California San Diego, La Jolla, CA, United States, (3)University of California San Diego, Department of Chemistry & Biochemistry, La Jolla, United States
VALIDATION OF AMMONIA DIFFUSIVE AND ACTIVE SAMPLERS IN A CONTROLLED ATMOSPHERE TEST FACILITY USING TRACEABLE PRIMARY STANDARD GAS MIXTURES (125944)
Nicholas Alvaro Martin1, Valerio Ferracci1, Nathan Cassidy1, Josh Hook1, Ross M Battersby1, Yuk S Tang2, Amy C M Stevens2, Matthew William Jones3, Christine F Braban2, Linda Gates4, Markus Hangartner5, Paolo Sacco6, Diego Pagani6 and John Hoffnagle7, (1)National Physical Laboratory, Teddington, United Kingdom, (2)Centre for Ecology and Hydrology, Pencuik, United Kingdom, (3)University of East Anglia, Norwich, United Kingdom, (4)Gradko International Ltd, Winchester, United Kingdom, (5)Passam AG, Mannedorf, Switzerland, (6)Fondazione Salvatore Maugeri, Padova, Italy, (7)Picarro, Inc., Santa Clara, CA, United States
Development of a new method for the measurement of Criegee intermediates in the gas and particle phase (130902)
Chiara Giorio1, Steven J Campbell2, Claudia Paijens1, Andrew J Wedlake1, Francesco Tampieri3, Andrea Tapparo3, Antonio Barbon3, Antonio Toffoletti3, Maurizio Bruschi4 and Markus Kalberer1, (1)University of Cambridge, Department of Chemistry, Cambridge, United Kingdom, (2)University of California Los Angeles, Atmospheric & Oceanic Sciences, Los Angeles, United States, (3)Università degli Studi di Padova, Department of Chemistry, Padova, Italy, (4)University of Milan - Bicocca, Department of Environmental Sciences, Milan, Italy
The Outdoor Atmospheric Simulation Chamber of Orleans-France (HELIOS) (162824)
Abdelwahid Mellouki1, Daële Véronique2, Benoit Grosselin1, Fabrice Peyroux1, Roland Benoit1, Yangang Ren1 and Mahmoud Idir1, (1)ICARE-CNRS, Orleans, France, (2)Centre National de la Recherche Scientifique (ICARE-CNRS)/OSUC, Institut de Combustion Aerothermique, Reactivite et Environnement, Orleans, France
Detection of methyl-, dimethyl- and diethylamine using a nitrate-based chemical ionization mass spectrometer (182158)
Tuija Jokinen and James N Smith, University of California Irvine, Irvine, CA, United States
Diuranl variations and characteristics of organic molecular composition and stable carbon isotope ratios of PM2.5 in Beijing during the "APEC Blue" (143435)
Hong Ren, Insititute of Atmospheric Physics, Chinese Academy of Sciences, IAP, Beijing, China, Songyun Fan, Insititute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, China and Pingqing Fu, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, China
Isotope Effect in Ozone Formation: Assessing the Relationship Between Photon Energy and Stabilization (191404)
Deborah Adrianna Gardner, Subrata Chakraborty and Mark H Thiemens, University of California San Diego, La Jolla, CA, United States
On the Chemical Characterization of Organic Matter in Rain at Mexico City. (134808)
Guillermo Montero-Martinez1, Gema Luz Andraca-Ayala1, Déborah Patricia Hernández-Nagay1, Angélica Mendoza-Trejo1, Joel Rivera-Arellano1, Anielka Rosado-Abon2 and Priyadarsi D. Roy3, (1)Centro de Ciencias de la Atmósfera. Universidad Nacional Autónoma de México, Ciudad de México, Mexico, (2)Instituto de Química. Universidad Nacional Autónoma de México, Ciudad de México, Mexico, (3)Instituto de Geología, Universidad Nacional Autónoma de México, Mexico City, Mexico
Spatial Variability of Perchlorate along a Traverse Route from Zhongshan Station to Dome A, East Antarctica (130430)
Su Jiang1, Jihong Cole-Dai2, Yuansheng Li1 and Chunlei An1, (1)Polar Research Institute of China, Shanghai, China, (2)South Dakota State University, Department of Chemistry and Biochemistry, Brookings, SD, United States
Tracing carbonaceous sources by using particulate carbon and sulfate in precipitation in Calgary, Alberta Canada (131425)
Chenqi Ge1, Kailyn Joyce Stenhouse1, Ke Du1, Zhenyu Xing1 and Ann-Lise Lise Norman2, (1)University of Calgary, Calgary, AB, Canada, (2)University of Calgary, Physics & Astronomy, Calgary, AB, Canada
The Role of Grain Size and Shape on the Electrical Conductivity of Volcanic Ash (145615)
Taylor W. Woods1, Kimberly D Genareau1 and Shelby Cloer2, (1)University of Alabama, Department of Geological Sciences, Tuscaloosa, AL, United States, (2)University of Alabama, Tuscaloosa, AL, United States
Unexpected Sources of Reactive Oxygen Species in Natural Water (195660)
Tara Kahan and Jarod N Grossman, Syracuse University, Syracuse, NY, United States

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