A43D:
Laboratory Studies in Atmospheric Sciences II


Submit an Abstract to this Session


Session ID#: 58406

Session Description:
Laboratory studies are fundamental to developing the knowledge needed to understand atmospheric chemistry over a broad range of conditions and environments and applying that knowledge to observations and models of Earth’s atmosphere. This session focuses on laboratory studies in areas including, but not limited to:  gas-phase kinetics (e.g. reactions involving OH, Cl, O3, NO3, Criegee intermediates), heterogeneous chemistry (e.g. reactive uptake, interfacial processes), aqueous-phase chemistry (e.g. hydrolysis, photochemistry), chamber studies (e.g. VOC oxidation), spectroscopy (e.g. cross sections, quantum yields), aerosol properties (e.g. SOA formation and aging, nucleation), and reaction mechanism development (e.g. isoprene, monoterpenes, VOCs). The primary focus is on studies in which the laboratory effort plays a central role in producing scientific results. Presentations on the development of instrumentation and methods that enhance laboratory studies are also encouraged, as are modeling and theoretical studies that incorporate laboratory data or that present results where no laboratory data yet exist.
Primary Convener:  David M Wilmouth, Harvard University, Cambridge, United States
Conveners:  James B Burkholder, NOAA ESRL, Chemical Sciences Laboratory, Boulder, CO, United States, John D Crounse, California Institute of Technology, Pasadena, United States and Neil McPherson Donahue, Carnegie Mellon University, Center for Atmospheric Particle Studies, Pittsburgh, United States
Primary Liaison:  David M Wilmouth, Harvard University, Cambridge, United States
Chairs:  David M Wilmouth, Harvard University, Cambridge, United States, James B Burkholder, NOAA ESRL, Chemical Sciences Laboratory, Boulder, CO, United States, John D Crounse, California Institute of Technology, Pasadena, United States and Neil McPherson Donahue, Carnegie Mellon University, Center for Atmospheric Particle Studies, Pittsburgh, United States
OSPA Liaison:  David M Wilmouth, Harvard University, Cambridge, United States
Index Terms:

0317 Chemical kinetic and photochemical properties [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0340 Middle atmosphere: composition and chemistry [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0365 Troposphere: composition and chemistry [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0394 Instruments and techniques [ATMOSPHERIC COMPOSITION AND STRUCTURE]

Abstracts Submitted to this Session:

Unseen Impacts of Organic Sulfur from Lower Sulfur Dioxide on Air Quality and Aerosol Properties (398502)
Jason D Surratt1, Matthieu Riva2, Yuzhi Chen3, Yue Zhang4, Ziying Nancy Lei5, Nicole Olson6, Hallie Boyer7, Shweta Narayan8, Lindsay Yee9, Hilary Green3, Tianqu Cui10, Zhenfa Zhang11, Karsten Baumann12, Michael Fort13, Eric S Edgerton13, Sri Hapsari Budisulistiorini3, Caitlin Rose3, Igor Ribeiro14, Erickson Oliveira15, Sophie Szopa16, Yue Zhao17, Eliane Gomes Alves18, Suzane S de Sá19, Weiwei Hu20, Eladio Knipping21, Stephanie Shaw22, Cristine Machado15, Sergio Duvoisin14, Rodrigo Augusto Ferreira de Souza14, Jose L Jimenez23, Marianne Glasius24, Allen H Goldstein25, Avram Gold26, Havala Olson Taylor Pye27, Barbara J Turpin11, William Vizuete3, Scot T Martin28, Joel A Thornton29, Cari S Dutcher30 and Andrew P Ault31, (1)University of North Carolina at Chapel Hill, Department of Chemistry, Chapel Hill, United States, (2)Pullman, WA, United States, (3)University of North Carolina at Chapel Hill, Chapel Hill, NC, United States, (4)University of North Carolina at Chapel Hill, Department or Environmental Sciences and Engineering, Gillings School of Global Public Health, Chapel Hill, United States, (5)University of Michigan, Department of Environmental Health, Ann Arbor, MI, United States, (6)University of Michigan Ann Arbor, Department of Chemistry, Ann Arbor, MI, United States, (7)Carnegie Mellon University, Pittsburgh, United States, (8)University of Minnesota, Minneapolis, MN, United States, (9)University of California Berkeley, Department of Environmental Science, Policy, & Management, Berkeley, CA, United States, (10)University of North Carolina at Chapel Hill, Chapel Hill, United States, (11)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, United States, (12)University of North Carolina, Chapel Hill, Department of Environmental Science and Engineering, Gillings School of Global Public Health, Chapel Hill, United States, (13)Atmospheric Research & Analysis, Inc., Cary, NC, United States, (14)Universidade do Estado do Amazonas, Manaus, Brazil, (15)Federal University of Amazonas, Manaus, Brazil, (16)LSCE Laboratoire des Sciences du Climat et de l'Environnement, Gif-Sur-Yvette Cedex, France, (17)University of Washington, Department of Atmospheric Sciences, Seattle, WA, United States, (18)INPA National Institute of Amazonian Research, Climate and Environment Department, Manaus, Brazil, (19)Harvard University, School of Engineering and Applied Sciences, Cambridge, MA, United States, (20)Chinese Academy Of Sciences, Guangzhou, China, (21)Electric Power Research Institute, Washington, DC, United States, (22)Electric Power Research Institute, Palo Alto, CA, United States, (23)Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado Boulder, Boulder, United States, (24)Aarhus University, Department of Chemistry, Aarhus C, Denmark, (25)University of California Berkeley, Department of Civil & Environmental Engineering, Berkeley, CA, United States, (26)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, NC, United States, (27)US Environmental Protection Agency, Center for Environmental Measurement and Modeling, Durham, United States, (28)Harvard University, Department of Earth and Planetary Sciences, Cambridge, MA, United States, (29)University of Washington, Department of Atmospheric and Climate Science, Seattle, United States, (30)University of Minnesota Twin Cities, Minneapolis, MN, United States, (31)University of Michigan Ann Arbor, Department of Chemistry, Ann Arbor, United States
Explicit Mass Spectrometric Determination of Isoprene Epoxydiol (IEPOX)-Derived Secondary Organic Aerosol with a Developed Hydrophilic Interaction Liquid Chromatography (HILIC) Method (429368)
Tianqu Cui1, Zhexi Zeng2, Erickson Oliveira3, Zhenfa Zhang4, Yuzhi Chen2, Yue Zhang5, Caitlin Rose2, Sri Hapsari Budisulistiorini2, Leonard Collins2, Wanda M Bodnar2, Rodrigo Augusto Ferreira de Souza6, Scot T. Martin7, Cristine Machado3, Barbara J Turpin4, Avram Gold8, Andrew P Ault9 and Jason D Surratt4, (1)University of North Carolina at Chapel Hill, Chapel Hill, United States, (2)University of North Carolina at Chapel Hill, Chapel Hill, NC, United States, (3)Federal University of Amazonas, Manaus, Brazil, (4)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, United States, (5)University of North Carolina at Chapel Hill, Department or Environmental Sciences and Engineering, Gillings School of Global Public Health, Chapel Hill, United States, (6)Universidade do Estado do Amazonas, Manaus, Brazil, (7)Harvard University, Cambridge, MA, United States, (8)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, NC, United States, (9)University of Michigan Ann Arbor, Department of Chemistry, Ann Arbor, United States
Interpreting Complex Mass Spectrometric Measurements from Laboratory Chamber Experiments (445364)
Abigail Koss1, Jordan Krechmer2, Martin Breitenlechner3, Alexander Zaytsev4, Brian M Lerner2, Kevin Nihill1, Christopher Y Lim1, Joseph R Roscioli5, Jonathan P. Franklin1, Joshua D Shutter6, Joshua L Cox7, Joshua Moss8, James Rowe1, Manjula R Canagaratna5, Frank N Keutsch9, Douglas R Worsnop5 and Jesse H Kroll1, (1)Massachusetts Institute of Technology, Civil and Environmental Engineering, Cambridge, MA, United States, (2)Aerodyne Research Inc., Billerica, United States, (3)Harvard University, Paulson School of Engineering and Applied Sciences, Cambridge, MA, United States, (4)Harvard University, School of Engineering and Applied Sciences, Cambridge, United States, (5)Aerodyne Research, Inc., Billerica, MA, United States, (6)Harvard University, Department of Chemistry and Chemical Biology, Cambridge, United States, (7)Harvard University, Department of Chemistry and Chemical Biology, Cambridge, MA, United States, (8)Massachusetts Institute of Technology, Civil and Environmental Engineering, Cambridge, CA, United States, (9)Harvard University, School of Engineering and Applied Sciences, Department of Chemistry and Chemical Biology and Department of Earth and Planetary Sciences, Cambridge, MA, United States
Comprehensive Study of Oxidation of Aromatic Compounds in the Urban Atmosphere (359859)
Alexander Zaytsev1, Martin Breitenlechner2, Abigail Koss3, Kevin Nihill3, Christopher Y Lim3, Brian M Lerner4, Jordan Krechmer4, James Rowe3, Joseph R Roscioli5, Jonathan P. Franklin3, Joshua L Cox6, Joshua D Shutter7, Joshua Moss8, Manjula R Canagaratna9, Douglas R Worsnop9, Jesse H Kroll3 and Frank N Keutsch10, (1)Harvard University, School of Engineering and Applied Sciences, Cambridge, United States, (2)Harvard University, Paulson School of Engineering and Applied Sciences, Cambridge, MA, United States, (3)Massachusetts Institute of Technology, Civil and Environmental Engineering, Cambridge, MA, United States, (4)Aerodyne Research Inc., Billerica, United States, (5)Aerodyne Research Inc., Billerica, MA, United States, (6)Harvard University, Department of Chemistry and Chemical Biology, Cambridge, MA, United States, (7)Harvard University, Department of Chemistry and Chemical Biology, Cambridge, United States, (8)Massachusetts Institute of Technology, Civil and Environmental Engineering, Cambridge, CA, United States, (9)Aerodyne Research, Inc., Billerica, MA, United States, (10)Harvard University, School of Engineering and Applied Sciences, Department of Chemistry and Chemical Biology, and Department of Earth and Planetary Sciences, Cambridge, MA, United States
Developing a quantitative understanding of peroxy radical autoxidation and gas-phase dimer formation from the oxidation of monoterpene (350927)
Yue Zhao, Shanghai Jiao Tong University, School of Environmental Science and Engineering, Shanghai, China, Joel A Thornton, University of Washington, Department of Atmospheric and Climate Science, Seattle, United States and Havala Olson Taylor Pye, US Environmental Protection Agency Research Triangle Park, Durham, NC, United States
Unimolecular reactions of peroxy radical in the oxidation of α-pinene and β-pinene by hydroxyl radical (451973)
Lu Xu, California Institute of Technology, Pasadena, CA, United States, Kristian Holten Møller, Santa Fe, NM, United States, John D Crounse, California Institute of Technology, Pasadena, United States, Henrik Kjaergaard, University of Copenhagen, Department of Chemistry, Copenhagen, Denmark and Paul O Wennberg, California Institute of Technology, Division of Geological and Planetary Sciences, Pasadena, United States
OH Radical-initiated Oxidation of (E)- and (Z)-β-ocimene in the Presence of NOx at Different Relative Humidities: Secondary Organic Aerosol Yields, Organic Nitrate Formation and Hydrolysis (437863)
Thilina Jayarathne1, Ana C Morales1, Jonathan Hall Slade Jr2 and Paul B Shepson3,4, (1)Purdue University, Department of Chemistry, West Lafayette, IN, United States, (2)University of California San Diego, Department of Chemistry & Biochemistry, La Jolla, CA, United States, (3)Stony Brook University, School of Marine and Atmospheric Sciences, Stony Brook, United States, (4)Purdue University, Departments of Chemistry, and Earth, Atmospheric, and Planetary Sciences, West Lafayette, IN, United States
Chemistry at the surface of titanium-containing minerals: implications for air quality and aerosol composition (466880)
Sarah A Styler1, Maya Abou-Ghanem1, Laura C Matchett1, Ming Lyu2, Andrew Locock3, Mario Schmidt1 and Shawn M Jansen van Beek1, (1)University of Alberta, Department of Chemistry, Edmonton, AB, Canada, (2)NOAA, Chemical Sciences Laboratory, Boulder, United States, (3)University of Alberta, Earth and Atmospheric Sciences, Edmonton, AB, Canada

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