Dissolution–precipitation processes governing the carbonation and silicification of the serpentinite sole of the New Caledonia ophiolite

Friday, 19 December 2014
Marc Ulrich1, Manuel Munoz2, Stephane Guillot2, Michel Cathelineau3, Christian Picard4, Benoit Quesnel5, Philippe Boulvais5 and Clement Couteau6, (1)Institut de Physique du Globe Strasbourg, Strasbourg Cedex, France, (2)Institut des Sciences de la Terre (ISTerre), CNRS - Université Joseph Fourier, Grenoble, France, (3)Universite de Lorraine, Georessources, Vandoeuvre-les-Nancy, France, (4)Université de Besançon, Laboratoire chrono-environnement, Besançon, France, (5)Géosciences Rennes, Rennes Cedex, France, (6)Koniambo Nickel SAS, Koné, New Caledonia
The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO2. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.