Simultaneous measurement of density and sound velocity of liquid Fe-C at high pressure

Abstract:

Seismological and experimental studies show that the Earth’s outer core is approximately 10% less dense than molten iron at the core pressure and temperature conditions, implying that some light elements exist in the core. The effect of light elements on density and bulk modulus of liquid iron is necessary for estimating of these core compositions. Sound velocity of liquid iron alloys is also important for identifying light elements in the core by comparison with observed seismic data.

 In this study, we have measured density and sound velocity of liquid Fe-C at SPring-8 beamline BL22XU using a DIA-type cubic anvil press (SMAP-I). Density was measured using X-ray absorption method (Katayama et al., 1993). We newly installed sound velocity measurement system using pulse-echo overlapping method (Higo et al., 2009) in this beamline. P-wave signals with a frequency of 35-37 MHz were generated and received by LiNbO₃ transducer. Buffer rod and backing plated were adopted single-crystal sapphire. The sample length at high pressure and high temperature were measured from absorption contrast between sample and sapphire.

 We measured velocity and density of liquid Fe-C between 1.1-2.8 GPa and 1480-1740 K. Obtained density and velocity of Fe-C was found to increase with pressure. In contrast, the effect of temperature on density and velocity was negative. The relationship between these two properties will be discussed.