A12C-01:
Understanding High Wintertime Ozone Events over an Oil and Natural Gas Production Region from Air Quality Model Perspective

Monday, 15 December 2014: 10:20 AM
Ravan Ahmadov1,2, Stuart A McKeen1,2, Michael Trainer1, Robert M Banta3, Steven S Brown4, Peter M Edwards5, Gregory J Frost1,2, Jessica Gilman6, Detlev Helmig7, Bryan Johnson8, Anna Karion9, Abigail Koss7, Brian M Lerner10, Samuel J Oltmans9, James M Roberts3, Russell C Schnell6, Patrick R Veres11, Carsten Warneke11, Eric J Williams6, Robert J Wild12, Bin Yuan1,2, Robert J Zamora13, Gabrielle Petron2, Joost A De Gouw14 and Jeff Peischl1,2, (1)NOAA, Earth System Research Laboratory, Boulder, CO, United States, (2)Cooperative Institute for Research in Environmental Sciences, Boulder, CO, United States, (3)NOAA/ESRL, Boulder, CO, United States, (4)NOAA Earth System Research Lab, Chemical Sciences Division, Boulder, CO, United States, (5)CIRES, Boulder, CO, United States, (6)NOAA ESRL, Boulder, CO, United States, (7)University of Colorado at Boulder, Boulder, CO, United States, (8)NOAA Boulder, ESRL/GMD, Boulder, CO, United States, (9)University of Colorado at Boulder, CIRES, Boulder, CO, United States, (10)NOAA, Earth System Research La, Boulder, CO, United States, (11)NOAA Boulder, Boulder, CO, United States, (12)Colorado University/NOAA/ESRL, Boulder, CO, United States, (13)NOAA/OAR R/PSD2, Boulder, CO, United States, (14)NOAA Earth System Research Lab, Boulder, CO, United States
Abstract:
The huge increase in production of oil and natural gas has been associated with high wintertime ozone events over some parts of the western US. The Uinta Basin, UT, where oil and natural gas production is abundant experienced high ozone concentrations in winters of recent years, when cold stagnant weather conditions were prevalent. It has been very challenging for conventional air quality models to accurately simulate such wintertime ozone pollution cases. Here, a regional air quality model study was successfully conducted for the Uinta Basin by using the WRF-Chem model. For this purpose a new emission dataset for the region’s oil/gas sector was built based on atmospheric in-situ measurements made during 2012 and 2013 field campaigns in the Uinta Basin.

The WRF-Chem model demonstrates that the major factors driving high ozone in the Uinta Basin in winter are shallow boundary layers with light winds, high emissions of volatile organic compounds (VOC) compared to nitrogen oxides emissions from the oil and natural gas industry, enhancement of photolysis rates and reduction of O3 dry deposition due to snow cover. We present multiple sensitivity simulations to quantify the contribution of various factors driving high ozone over the Uinta Basin. The emission perturbation simulations show that the photochemical conditions in the Basin during winter of 2013 were VOC sensitive, which suggests that targeting VOC emissions would be most beneficial for regulatory purposes. Shortcomings of the emissions within the most recent US EPA (NEI-2011, version 1) inventory are also discussed.