A33L:
Laboratory Studies in Atmospheric Sciences I Posters


Submit an Abstract to this Session


Session ID#: 56628

Session Description:
Laboratory studies are fundamental to developing the knowledge needed to understand atmospheric chemistry over a broad range of conditions and environments and applying that knowledge to observations and models of Earth’s atmosphere. This session focuses on laboratory studies in areas including, but not limited to:  gas-phase kinetics (e.g. reactions involving OH, Cl, O3, NO3, Criegee intermediates), heterogeneous chemistry (e.g. reactive uptake, interfacial processes), aqueous-phase chemistry (e.g. hydrolysis, photochemistry), chamber studies (e.g. VOC oxidation), spectroscopy (e.g. cross sections, quantum yields), aerosol properties (e.g. SOA formation and aging, nucleation), and reaction mechanism development (e.g. isoprene, monoterpenes, VOCs). The primary focus is on studies in which the laboratory effort plays a central role in producing scientific results. Presentations on the development of instrumentation and methods that enhance laboratory studies are also encouraged, as are modeling and theoretical studies that incorporate laboratory data or that present results where no laboratory data yet exist.
Primary Convener:  David M Wilmouth, Harvard University, Cambridge, United States
Conveners:  James B Burkholder, NOAA ESRL, Chemical Sciences Laboratory, Boulder, CO, United States, John D Crounse, California Institute of Technology, Pasadena, CA, United States and Neil McPherson Donahue, Carnegie Mellon University, Center for Atmospheric Particle Studies, Pittsburgh, United States
Primary Liaison:  David M Wilmouth, Harvard University, Cambridge, United States
Chairs:  Neil McPherson Donahue, Carnegie Mellon University, Center for Atmospheric Particle Studies, Pittsburgh, United States and Carl Percival, NASA Jet Propulsion Laboratory, California Institute of Technology, Pasadena, United States
OSPA Liaison:  David M Wilmouth, Harvard University, Cambridge, United States
Index Terms:

0317 Chemical kinetic and photochemical properties [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0340 Middle atmosphere: composition and chemistry [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0365 Troposphere: composition and chemistry [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0394 Instruments and techniques [ATMOSPHERIC COMPOSITION AND STRUCTURE]

Abstracts Submitted to this Session:

Rate Constants for the Reactions of OH with Several Unsaturated HFCs (Hydrofluoroolefins) Over the Pressure Range 10-900 Torr and the Temperature Range 230-340 K. (368388)
Victor Khamaganov, National Institute of Standards and Technology Gaithersburg, Gaithersburg, MD, United States, Vladimir L Orkin, National Institute of Standards and Technology, Gaithersburg, MD, United States and Michael J Kurylo III, GESTAR / USRA, Greenbelt, MD, United States
Atmospheric Chemistry of c-C5HF7and c-C5F8: OH Reaction Rate Coefficients, Degradation Products, Infrared Spectra, and Global Warming Potentials (374243)
James B Burkholder, NOAA ESRL, Chemical Sciences Laboratory, Boulder, CO, United States, Tomasz Gierczak, NOAA Boulder, Boulder, United States, François Bernard, Earth System Research Laboratory, Boulder, CO, United States and Dimitrios K Papanastasiou, Independent Researcher, Buffalo, NY, United States
RO2 + RO2 chemistry of small peroxy radicals (442200)
John D Crounse, California Institute of Technology, Pasadena, CA, United States and Paul O Wennberg, California Institute of Technology, Division of Geological and Planetary Sciences, Pasadena, United States
Laboratory UV Spectroscopic Studies of Rayleigh Scattering Cross Sections and Equilibrium Constants (447379)
David M Wilmouth, Harvard University, Cambridge, United States, David S Sayres, Harvard University, Cambridge, MA, United States and J. Eric Klobas, Harvard University, Harvard John A Paulson School of Engineering and Applied Sciences, Cambridge, United States
Infrared absorption cross-sections of fluorinated molecules for improved global warming potential calculations (448467)
Kimberly Strong1, Paul J Godin1,2, Karine Le Bris3, Hayden Allen Johnson4, Romina Piunno1, Alex Cabaj1, Claire MacDougall3 and Li-Hong Xu5, (1)University of Toronto, Department of Physics, Toronto, ON, Canada, (2)York University, Toronto, ON, Canada, (3)St. Francis Xavier University, Department of Physics, Antigonish, NS, Canada, (4)University of California San Diego, Scripps Institution of Oceanography, San Diego, United States, (5)University of New Brunswick, Department of Physics, Saint John, NB, Canada
Formation of Organosulfur Compounds in the Aqueous Phase Through Transition Metal Ions Catalyzed Reactions (387189)
Liubin Huang, University of California San Diego, La Jolla, CA, United States, Ellen M Coddens, University of California San Diego, Department of Chemistry and Biochemistry, La Jolla, United States, Vicki H Grassian, University of California San Diego, Chemistry and Biochemistry, La Jolla, United States and Richard E Cochran, University of California San Diego, La Jolla, United States
Effects of Sodium Chloride on Anthracene Photolysis Kinetics in Aqueous, Organic and Mixed Aqueous-Organic Phases (419120)
Alexa Stathis and Tara Kahan, Syracuse University, Syracuse, NY, United States
Anthracene Photolysis Kinetics in Salty Water and Ice (392919)
Annastacia Stubbs and Tara Kahan, Syracuse University, Syracuse, NY, United States
Gas-Surface Uptake of Gaseous Oxidized Mercury on Inorganic Salts (395376)
Na Mao1, John Antley2, Matthew Blake Cooper3, Neil Shah2, Anuradha Kadam2 and Alexei F Khalizov1, (1)New Jersey Institute of Technology, Chemistry and Environmental Science, Edison, NJ, United States, (2)New Jersey Institute of Technology, Newark, NJ, United States, (3)New Jersey Institute of Technology, Center For Solar-Terrestrial Research, Edison, United States
Evaluating the Acidity Enhancement of Carboxylic Acids and its Effect on Photochemistry on the Surface of Water (438356)
Marcelo I Guzman, Alexis J. Eugene and Sha-Sha Xia, University of Kentucky, Department of Chemistry, Lexington, KY, United States
Smog Chamber Experiments on Secondary Organic Aerosol (SOA) and Nitrate Aerosol Generation from Dark Condition Aging of Toluene and Limonene SOA (430767)
Sathiyamurthi Ramasamy1, Tomoki Nakayama2,3, Takashi Imamura1, Yoshizumi J Kajii1,4 and Kei Sato1, (1)National Institute for Environmental Studies, Tsukuba, Japan, (2)Nagoya University, Nagoya, Japan, (3)Nagasaki University, Nagasaki, Japan, (4)Kyoto University, Sakyo-ku Kyoto, Japan
Formation of Secondary Aerosol through Oxidation of Agricultural Amines and Reduced Sulfur Compounds: A Chamber Study (393423)
Paul Van Rooy, University of California Riverside, Riverside, CA, United States, Kathleen Purvis-Roberts, W.M. Keck Science Department, Claremont, CA, United States, Philip J Silva, USDA-ARS, Bowling Green, KY, United States and David R Cocker III, University of California, Riverside, Department of Chemical and Environmental Engineering, Riverside, United States
Probing the Thermal Behaviors of α-pinene, Δ3-carene and IEPOX SOA using Cluster Analysis (427471)
Ziyue Li1, Emma D'Ambro2, Siegfried Schobesberger3, Taylor Helgestad4, Joel A Thornton5, John Shilling6 and Christopher D Cappa4, (1)University of California Davis, Atmospheric Science, Davis, CA, United States, (2)Univ Washington - Seattle, Seattle, WA, United States, (3)University of Washington Seattle Campus, Department of Atmospheric Sciences, Seattle, WA, United States, (4)University of California Davis, Civil and Environmental Engineering, Davis, CA, United States, (5)University of Washington, Department of Atmospheric and Climate Science, Seattle, United States, (6)Pacific Northwest National Laboratory, Richland, United States
Study of the Effects of NO on Secondary Organic Aerosol and Ozone Formation using New Methods (463116)
Weihan Peng, University of California Riverside, Riverside, CA, United States and David R Cocker III, University of California, Riverside, Department of Chemical and Environmental Engineering, Riverside, United States
Photochemical Processing of Filter Collected α-pinene SOA; Molecular Composition Changes and Absorption Properties (434757)
Emma Walhout, College of William and Mary, Chemistry, Williamsburg, VA, United States and Rachel O'Brien, College of William and Mary, Chemistry, Cambridge, VA, United States
Depth Probing Organic Particles with Easy Ambient Sonic-Spray Ionization Mass Spectrometry (355105)
Lisa M Wingen, University of California Irvine, Irvine, CA, United States and Barbara J Finlayson-Pitts, University of California Irvine, Chemistry, Irvine, United States
Towards Direct Molecular Speciation of Atmospheric Gaseous Oxidized Mercury (400860)
Alexei F Khalizov, New Jersey Institute of Technology, Chemical and Materials Engineering, Edison, NJ, United States; New Jersey Institute of Technology, Chemistry and Environmental Science, Edison, NJ, United States, Francisco Guzman, New Jersey Institute of Technology, Chemical and Materials Engineering, Newark, NJ, United States, Matthew Blake Cooper, New Jersey Institute of Technology, Center For Solar-Terrestrial Research, Edison, United States, John Antley, New Jersey Institute of Technology, Newark, NJ, United States and Joseph Bozzelli, New Jersey Institute of Technology, Chemistry and Environmental Science, Newark, United States
Extrapolation of thermal radiation signals in the Single Particle Soot Photometer (369059)
Dr. Joshua Peter Schwarz, PhD, NOAA Boulder, Chemical Sciences Division, Boulder, CO, United States
Application of Isotopic Labelling Techniques with Chemical Ionization Mass Spectrometry for the Elucidation of Molecular Structural Information (379215)
Patrick R Veres, NOAA ESRL Chemical Sciences Division, Boulder, CO, United States, J A Neuman, Cooperative Institute for Research in Environmental Sciences (CIRES), Boulder, United States and Carsten Warneke, NOAA Chemical Sciences Laboratory, Boulder, United States; Cooperative Institute for Research in Environmental Sciences, Boulder, CO, United States
Analyzing Organic Constituents on Atmospheric Particulate Matters by Comprehensive Two-Dimensional Gas Chromatography-Mass Spectrometry (GCxGC-MS) (388340)
Chang-Feng Ou-Yang1, Yi-Jun Chen2, Chung-Te Lee3, Kai-Hsien Chi4, Neng-Huei Lin1 and Jia-lin Wang2, (1)National Central University, Department of Atmospheric Sciences, Taoyuan, Taiwan, (2)National Central University, Department of Chemistry, Taoyuan, Taiwan, (3)National Central University, Graduate Institute of Environmental Engineering, Taoyuan, Taiwan, (4)National Yang Ming University, Institute of Environmental and Occupational Health Sciences, Taipei, Taiwan
Investigation of the Mechanism of the Reaction of Soil Organic Matter with N2O5 (396494)
Robert F Hansen1, Rebecca Abney1, Mark Engelhard2, Daniel P Veghte3, Swarup China4 and Jonathan D. Raff5, (1)Indiana University Bloomington, Bloomington, IN, United States, (2)Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, United States, (3)Pacific Northwest National Laboratory, Richland, WA, United States, (4)Pacific Northwest National Laboratory, Environmental Molecular Sciences Laboratory, Richland, United States, (5)Indiana University, O'Neill School of Public and Environmental Affairs, Bloomington, IN, United States
Measuring Changes in Acidity upon Freezing of Acetic Acid and Sodium Acetate Solutions (397934)
Prof. Rebecca R H Michelsen, Randolph-Macon College, Department of Chemistry, Ashland, VA, United States, Caitlin Spencer, Randolph-Macon College, Chemistry, Ashland, VA, United States and Cade English, Randolph-Macon College, Chemistry, Ashland, United States
Do We Underestimate the Uptake Coefficient and Gas-Particle Partitioning Coefficient for Peroxides and Carbonyl Compounds in the Ambient Atmosphere？ (426744)
Zhongming Chen1, Zhijiong Cao2, Xi Qian3, Mengru Qin3, Hengqing Shen1, Liubin Huang3, Huan Li3, Qinqin Wu3, Hao Liang3, Yin Wang3 and Yue Zhao3, (1)Peking University, College of Environmental Sciences and Engineering, Beijing, China, (2)University of California, Los Angeles, Geography, Los Angeles, United States, (3)Peking University, Beijing, China
Molecularly Detailed Measurement of Condensed Phase Atmospheric Aerosol Processes in Single Levitated Particles (448832)
Adam Birdsall, Harvard University, Department of Chemistry and Chemical Biology, Cambridge, MA, United States, Jack C Hensley, Harvard University, School of Engineering and Applied Sciences, Cambridge, MA, United States and Frank N Keutsch, Harvard University, School of Engineering and Applied Sciences, Department of Chemistry and Chemical Biology, and Department of Earth and Planetary Sciences, Cambridge, MA, United States
Aqueous-phase Secondary Formation and Transformations of Dicarboxylic acids and Related Compounds (465332)
Chandra Mouli Pavuluri1, Subba Rao Devineni1, Peisen Li1, Yanlin Zhang2, Pingqing Fu3 and Cong-Qiang Liu4, (1)Institute of Surface-Earth System Science, Tianjin University, Tianjin, China, (2)NUIST Nanjing University of Information Science and Technology, Nanjing, China, (3)Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin, China, (4)Chinese Academy Sciences, Guiyang, Guizhou, China
Evidence of the Direct Reaction Between Ozone and Molecular Components in Epicuticular Waxes of Olive Leaves and Grape Berry Skins (363690)
Teresa Longin1, Vanessa Huerta Navarro1, Beatriz Romero1, Caitlin Smith1, Taryn Rogoff1, Tavleen Kochar2 and David Soulsby1, (1)University of Redlands, Chemistry, Redlands, CA, United States, (2)University of North Carolina, Chapel Hill, Chemistry, Chapel Hill, NC, United States
Laboratory Study for Gaseous Mercury Uptake by Atmospheric Water (430435)
Satoshi Irei, National Institute for Minamata Disease, Environment and Public Health, Minamata, Japan
Photolysis of Aqueous Atmospheric Aerosol Mimics (459819)
Melissa M Galloway, Daisy N Grace, Jacqueline R Sharp and Rachael E Holappa, Lafayette College, Chemistry, Easton, PA, United States
Prevalence of Isomers in the Atmosphere and Their Impacts on Interpreting Laboratory Data (400499)
Gabriel A Isaacman-VanWertz1, Bernard Aumont2, Manjula R Canagaratna3, Paola Massoli4, John B Nowak4, Jordan Krechmer5, Rachel O'Brien6, Jesse H Kroll7 and Douglas R Worsnop3, (1)Virginia Tech, Civil and Environmental Engineering, Blacksburg, VA, United States, (2)University Paris-Est Créteil Val de Marne, Créteil Cedex, France, (3)Aerodyne Research, Inc., Billerica, MA, United States, (4)Aerodyne Research Inc., Billerica, MA, United States, (5)Aerodyne Research Inc., Billerica, United States, (6)College of William and Mary, Chemistry, Cambridge, VA, United States, (7)Massachusetts Institute of Technology, Civil and Environmental Engineering, Cambridge, MA, United States
Laboratory Studies of Airborne Biological Particles and Common Interferents Using Multiple Ultra-Violet Light Induced Fluorescence (UV-LIF) Instrumentation (430956)
Elizabeth Forde1, Martin William Gallagher2, Virginia E Foot3, Maurice Walker3, Alexis Attwood4, Gary Granger4, Roland Sarda Esteve5, Ian Crawford2, Paul H Kaye6, Warren R Stanley6 and David O Topping7, (1)University of Manchester, Manchester, M13, United Kingdom, (2)University of Manchester, Manchester, United Kingdom, (3)Defence Science and Technology Laboratory, Salisbury, United Kingdom, (4)Droplet Measurement Technologies, Longmont, CO, United States, (5)Laboratoire des Sciences du Climat et de l'Environnement, Gif-Sur-Yvette Cedex, France, (6)University of Hertfordshire, Hatfield, United Kingdom, (7)University of Manchester, School of Earth, Atmospheric and Environmental Science, Manchester, United Kingdom
The reaction between potassium chloride and carboxylic acid in internally mixed aerosols (366741)
Shufeng Pang, Xiaowei Wang and Yun-Hong Zhang, Beijing Institute of Technology, Beijing, China
Modified Combustion Efficiency, Physicochemical, and Optical Properties of Biomass Burning Aerosol from Sources Native to Sub-Saharan Africa (370925)
Solomon Bililign1, Damon Michael Smith2, Marc Nicholas Fiddler3 and Emmanuel Sarpong1, (1)North Carolina A & T State University, Physics, Greensboro, United States, (2)North Carolina A & T State University, Physics, Greensboro, NC, United States, (3)North Carolina A & T State University, NOAA-ISET Center, Greensboro, NC, United States
Effective Refractive Index Retrieval and Single Scattering Albedo Implications of Dry-Generated Mineral Dust Component Aerosol (363987)
Jillian Morang1, Tyler Galpin1 and Margaret E Greenslade2, (1)University of New Hampshire Main Campus, Durham, NH, United States, (2)University of New Hampshire, Lowell, MA, United States
Spatially Resolved Hyperspectral Optical Extinction Measurements of Carbonaceous Particulate in a Nitrogen-Diluted Ethylene/Air Diffusion Flame and Implications for the Angstrom Exponent (379566)
Rachelle S Jacobson1, Erin M Adkins2, Monica Flores3, Michelle Bailey2 and John Houston Miller4, (1)George Washington University, Washington, DC, United States, (2)George Washington University, Chemistry, Washington, DC, United States, (3)The George Washington University, Chemistry, Washington, DC, United States, (4)The George Washington University, Washington, DC, United States
Monitoring Brown Carbon Formation in Real Time from Multiphase Reactions of Amines and Carbonyls (391838)
Jennifer Faust1, Kevin A Wokosin1, Shayna Vicker2 and Erika Womack1, (1)College of Wooster, Chemistry, Wooster, OH, United States, (2)College of Wooster, Biochemistry & Molecular Biology, Wooster, United States
A Novel Humidity-Controlled Integrated Extinctiometer and Nephelometer to Quantify the Effects of Water on Light Absorption by Black and Brown Carbon (456290)
Manvendra Krishna Dubey1, Jared Lam2, Christian Carrico2, Dian Romonosky3, Allison C Aiken4, Timothy Bruce Onasch5 and Andrew Freedman6, (1)Los Alamos National Laboratory, Earth and Environmental Sciences, Los Alamos, NM, United States, (2)New Mexico Institute of Mining and Technology, Socorro, NM, United States, (3)University of California Irvine, Irvine, CA, United States, (4)Los Alamos National Laboratory, Earth and Environmental Science Division, Los Alamos, NM, United States, (5)Aerodyne Research, Inc., Billerica, MA, United States, (6)Aerodyne Research Inc., Billerica, MA, United States
Optical properties of fresh biomass burning aerosol produced from realistic combustion of boreal peat (466075)
Ming Lyu1, Nianci Zhang2, Matthew S Ross3, Cora Young4, Daniel K Thompson5 and Sarah A Styler2, (1)NOAA, Chemical Sciences Laboratory, Boulder, United States, (2)University of Alberta, Department of Chemistry, Edmonton, AB, Canada, (3)MacEwan University, Department of Physical Sciences, Edmonton, Canada, (4)York University, Chemistry, Toronto, ON, Canada, (5)Natural Resources Canada - Canadian Forest Service, Edmonton, AB, Canada
Raman Intensities of Mobility-Size Selected Sub-micron Black Carbon Particles (417073)
Francis Oyebanjo, University of Maryland College Park, College Park, MD, United States, David C Doughty III, US Army Research Laboratory, White Sands Missile, NM, United States, Steven C Hill, US Army Research Laboratory, CISD, Adelphi, MD, United States and Akua A Asa-Awuku, University of Maryland, College Park, United States
Laboratory Studies of New Particle Formation from Ozonolysis of Sesquiterpenes (439255)
Jun Zhao, Qiduo Shao, Baoling Liang, Beining Zhou, Mingfu Cai, Kunpeng Chen, Qibin Sun and Jish Prakash, Sun Yat-sen University, School of Atmospheric Sciences, Guangzhou, China
Reactions of Amines and Organics with Methanesulfonic Acid as a Source for New Particle Formation in Air: Combined Experimental and Theoretical Studies (356175)
Veronique M Perraud, University of California Irvine, Irvine, CA, United States, Jing Xu, University of California, Irvine, Irvine, United States, R. Benny Gerber, Hebrew University of Jerusalem, Chemistry, Jerusalem, Israel and Barbara J Finlayson-Pitts, University of California Irvine, Chemistry, Irvine, United States

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