Novel Methods for Optically Measuring Whitecaps Under Natural Wave Breaking Conditions in the Southern Ocean

Breaking waves on the ocean surface mark areas of significant importance to air-sea flux estimates of gas, aerosols, and heat. Traditional methods of measuring whitecap coverage using digital photography can miss features that are small in size or do not show high enough contrast to the background. The geometry of the images collected captures the near surface, bright manifestations of the whitecap feature and miss a portion of the bubble plume that is responsible for the production of sea salt aerosols and the transfer of lower solubility gases. Here, a novel method for accurately measuring both the fractional coverage of whitecaps and the intensity and decay rate of whitecap events using above water radiometry is presented. The methodology was developed using data collected during the austral summer in the Atlantic sector of the Southern Ocean under a large range of wind (speeds of ~1 to 15 m s^-1) and wave (significant wave heights ~2 to 8 m) conditions as part of the Southern Ocean Gas Exchange experiment. Whitecap metrics were retrieved by employing a magnitude threshold based on the interquartile range of the radiance or reflectance signal for a single channel (411 nm) after a baseline removal, determined using a moving minimum/maximum filter. Breaking intensity and decay rate metrics were produced from the integration of, and the exponential fit to, radiance or reflectance over the lifetime of the whitecap. When compared to fractional whitecap coverage measurements obtained from high resolution digital images, radiometric estimates were consistently higher because they capture more of the decaying bubble plume area that is difficult to detect with photography. Radiometrically-retrieved whitecap measurements are presented in the context of concurrently measured meteorological (e.g., wind speed) and oceanographic (e.g., wave) data. The optimal fit of the radiometrically estimated whitecap coverage to the instantaneous wind speed, determined using ordinary least squares, showed a cubic dependence. Increasing the magnitude threshold for whitecap detection from 2 to 3(IQR) produced a wind speed-whitecap relationship most comparable to previously published and widely accepted wind speed-whitecap parameterizations.