Observations of whitecaps during HiWinGS, their dependence on wave field, and relation to gas transfer velocities

The High Wind Gas exchange Study (HiWinGS) presents the unique opportunity to gain new insights on the poorly understood aspects of air-sea interaction under high winds. The HiWinGS cruise took place in the North Atlantic during October and November 2013. Wind speeds exceeded 15 m s^-1 25% of the time, including 48 hrs with U10 > 20 m s^-1. Continuous measurements of turbulent fluxes of heat, momentum, and gas were taken from the bow of the R/V Knorr. Visible imagery was acquired from the port and starboard side of the flying bridge during daylight hours at 20Hz and directional wave spectra were obtained when on station from a wave rider buoy. Additional wave field statistics were computed from a laser altimeter as well as from a Wavewatch III hindcast.

Taking advantage of the range of physical forcing and wave conditions sampled during HiWinGS, we investigate how the fractional whitecap coverage (W) and gas transfer velocity (K) vary with sea state. We distinguish between windseas and swell based on a separation algorithm applied to directional wave spectra, allowing contrasting pure windseas to swell dominated periods. For mixed seas, system alignment is considered when interpreting results.

The four gases sampled during HiWinGS ranged from being mostly waterside controlled to almost entirely airside controlled. While bubble-mediated transfer appears to be small for moderately soluble gases like DMS, the importance of wave breaking turbulence transport has yet to be determined for all gases regardless of their solubility. This will be addressed by correlating measured K to estimates of active whitecap fraction (W_A) and turbulent kinetic energy dissipation rate (ε). W_A and ε are estimated from moments of the breaking crest length distribution derived from the imagery, focusing on young seas, when it is likely that large-scale breaking waves (i.e., whitecapping) will dominate the ε.